/ Home
/ SUBMISSION

/ The BJOC
/ Diamond Open Access
/ Journal Statistics
/ Editorial Board
/ Community
/ Call for papers

/ Latest Articles
/ Most accessed
/ Thematic issues
/ Volumes
/ Authors

/ Alerts

/ TWITTER
/ LINKEDIN
/ Mastodon
/ RSS FEED

Empty search

Article Type

Publication Date Range

Search Tips

This search combines search strings from the content search (i.e. "Full Text", "Author", "Title", "Abstract", or "Keywords") with "Article Type" and "Publication Date Range" using the AND operator.

Search Examples

aromatic	the word “aromatic”
aromatic aldehyde	the word “aromatic” OR “aldehyde”
+aromatic +aldehyde	both words “aromatic” AND “aldehyde”
+aromatic -aldehyde	the word “aromatic” but NOT “aldehyde”
“aromatic aldehyde”	the exact phrase “aromatic aldehyde”
benz*	words which begin with “benz”, such as “benzene” or “benzyl”
benz*yl	words that begin with “benz” and end with “yl”, such as “benzyl” or “benzoyl”
benzyl~	words that are close to the word “benzyl”, such as “benzoyl” (i.e., fuzzy search)

BROWSE
Latest Articles
Most accessed
thematic issues
volumes
authors

BROWSE

Latest Articles Most Accessed Thematic Issues Volumes Authors

Author

2 article(s) from Demchenko, Alexei V

Intramolecular glycosylation

Xiao G. Jia and
Alexei V. Demchenko

Beilstein J. Org. Chem. 2017, 13, 2028–2048, doi:10.3762/bjoc.13.201

PDF

Graphical Abstract

Scheme 1: The mechanistic outline of the intermolecular (a) and intramolecular (b) glycosylation reactions.

Jump to Scheme 1

Figure 1: Three general concepts for intramolecular glycosylation reactions.

Jump to Figure 1

Scheme 2: First intramolecular glycosylation using the molecular clamping.

Jump to Scheme 2

Scheme 3: Succinoyl as a flexible linker for intramolecular glycosylation of prearranged glycosides.

Jump to Scheme 3

Scheme 4: Template-directed cyclo-glycosylation using a phthaloyl linker.

Jump to Scheme 4

Scheme 5: Phthaloyl linker-mediated synthesis of branched oligosaccharides via remote glycosidation.

Jump to Scheme 5

Scheme 6: Molecular clamping with the phthaloyl linker in the synthesis of α-cyclodextrin.

Jump to Scheme 6

Scheme 7: m-Xylylene as a rigid tether for intramolecular glycosylation.

Jump to Scheme 7

Scheme 8: Oligosaccharide synthesis using rigid xylylene linkers.

Jump to Scheme 8

Scheme 9: Stereo- and regiochemical outcome of peptide-based linkers.

Jump to Scheme 9

Scheme 10: Positioning effect of donor and acceptor in peptide templated synthesis.

Jump to Scheme 10

Scheme 11: Synthesis of a trisaccharide using a non-symmetrical tether strategy.

Jump to Scheme 11

Scheme 12: Effect of ring on glycosylation with a furanose.

Jump to Scheme 12

Scheme 13: Rigid BPA template with various linkers.

Jump to Scheme 13

Scheme 14: The templated synthesis of maltotriose in complete stereoselectivity.

Jump to Scheme 14

Scheme 15: First examples of the IAD.

Jump to Scheme 15

Scheme 16: Long range IAD via dimethylsilane.

Jump to Scheme 16

Scheme 17: Allyl-mediated tethering strategy in the IAD.

Jump to Scheme 17

Scheme 18: IAD using tethering via the 2-naphthylmethyl group.

Jump to Scheme 18

Scheme 19: Origin of selectivity in boronic ester mediated IAD.

Jump to Scheme 19

Scheme 20: Arylborinic acid approach to the synthesis of β-mannosides.

Jump to Scheme 20

Figure 2: Facial selectivity during HAD.

Jump to Figure 2

Scheme 21: Possible mechanisms to explain α and β selectivity in palladium mediated IAD.

Jump to Scheme 21

Scheme 22: DISAL as the leaving group that favors the intramolecular glycosylation pathway.

Jump to Scheme 22

Scheme 23: Boronic acid as a directing group in the leaving group-based glycosylation method.

Jump to Scheme 23

Album

Review

Published 29 Sep 2017

Full text

2-Allylphenyl glycosides as complementary building blocks for oligosaccharide and glycoconjugate synthesis

Hemali D. Premathilake and
Alexei V. Demchenko

Beilstein J. Org. Chem. 2012, 8, 597–605, doi:10.3762/bjoc.8.66

PDF

Graphical Abstract

Scheme 1: Orthogonal strategy introduced by Ogawa et al.

Jump to Scheme 1

Scheme 2: Determination of the AP activation pathways.

Jump to Scheme 2

Scheme 3: AP building blocks in oligosaccharide synthesis.

Jump to Scheme 3

Album

Supp Info

Full Research Paper

Published 18 Apr 2012

Full text

Other Beilstein-Institut Open Science Activities

/ Help / Support & Contact / Alerts / Privacy Policy / Terms & Conditions / Impressum